132396-99-7Relevant articles and documents
The photosubstitution of iodide in (η5-C5H5)Fe(CO)2I. Synthesis of cyclopentadienyliron dicarbonyl- and carbonyl phosphine complexes containing η1-N-imidato(1-) ligands
Zakrzewski, Janusz
, p. 215 - 218 (1989)
The photoreaction of (η5-C5H5)Fe(CO)2I-diisopropylamine with succinimide and phthalimide gave the corresponding (η5-C5H5)Fe(CO)2-η1-N-imidato complexes, which were converted into the (η5-C5H5)Fe(CO)(PPh3)-η
Diethylammonium iodide as catalyst for the metal-free synthesis of 5-aryl-2-oxazolidinones from aziridines and carbon dioxide
Bresciani, Giulio,Bortoluzzi, Marco,Pampaloni, Guido,Marchetti, Fabio
, p. 4152 - 4161 (2021/05/19)
The catalytic potential of ammonium halide salts was explored in the coupling reaction of a model aziridine with carbon dioxide, highlighting the superior activity of [NH2Et2]I. Then, working at room temperature, atmospheric CO2 pressure and in the absenc
Nucleophilic Substitution in 1-Substituted 3-Iodobicyclopentanes. A New Synthetic Route to Functionalized Bicyclopentane Derivatives
Adcock, James L.,Gakh, Andrei A.
, p. 6206 - 6210 (2007/10/02)
Nucleophilic substitution of the iodine in 1-substituted 3-iodobicyclopentanes was investigated.The results of the reaction are strongly dependent on the nature of the nucleophile and the substituent.Whereas the trifluoromethyl derivative 2 is found to be inert in the reactions and gave substitution products only with organolithium reagents, the 1,3-diiodide 1 is much more reactive and affords normal substitution products with nitrogen bases and MeONa but gives propellane with Grignard and organolithium reagents and with triaryl(allkyl)phosphines.Other synthesized 3-iodobicyclopentanes did not give substitution products.A general scheme for the transformations of 1 is also proposed.
