132436-59-0

Basic information

• Product Name: (S)-(+)-methyl 3-methyl-4-phenylbutanoate
• Synonyms: (S)-(+)-methyl 3-methyl-4-phenylbutanoate
• CAS NO: 132436-59-0
• Molecular Weight: 192.258
• Mol File: 132436-59-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (S)-(+)-methyl 3-methyl-4-phenylbutanoate(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-(+)-methyl 3-methyl-4-phenylbutanoate(132436-59-0)
• EPA Substance Registry System: (S)-(+)-methyl 3-methyl-4-phenylbutanoate(132436-59-0)

Safety Data

• Hazardous Substances Data: 132436-59-0(Hazardous Substances Data)

Upstream product

• 63158-17-8 methyl (E)-4-phenyl-2-butenoate 
• 75-16-1 methylmagnesium bromide 
• 34541-75-8 methyl (Z)-4-phenyl-2-butenoate 
• 108-86-1 bromobenzene 
• 1517-68-6 (S)-1-phenylpropan-2-ol 
• 121-44-8 triethylamine 
• 103026-74-0 dimethyl 4-benzyl-2,6-dimethyl-1,4-dihydropyridine-3,5-dicarboxylate 
• 67-56-1 methanol 
• 1309251-32-8 (R)-1-phenylpropanyl-2-yl methansulfonate 
• 61342-56-1 (R)-1-phenylpropan-2-yl 4-methylbenzenesulfonate 
• 1572-95-8 (R)-1-phenyl-propan-2-ol 

Downstream Products

• 34126-21-1 (R)-3-methyl-4-phenylbutan-1-ol 

Relevant articles and documents

Exploration of a Chiral Cobalt Catalyst for Visible-Light-Induced Enantioselective Radical Conjugate Addition

Chiral catalysts tolerating photochemical reactions are in great demand for the vast development of visible-light-induced asymmetric synthesis. Now, chiral octahedral complexes based on earth-abundant metal and chiral N4 ligands are reported. One well-defined chiral CoII-complex is shown to be an efficient catalyst in the visible-light-induced conjugated addition of enones by alkyl and acyl radicals, providing synthetically valued chiral ketones and 1,4-dicarbonyls in 47–'99 % yields with up to 97:3 e.r.

Highly efficient copper(I) iodide-tolyl-BINAP-catalyzed asymmetric conjugate addition of methylmagnesium bromide to α,β-unsaturated esters

A highly efficient asymmetric conjugate addition of methylmagnesium bromide (MeMgBr) to α,β-unsaturated esters catalyzed by copper(I) iodide-tolyl-BNIP (CuI-Tol-BINAP) is described.