1327278-14-7

Basic information

• Product Name: 4-((3R,5S)-2-oxo-5-phenyl-morpholin-3-yl)phenyl acetate
• Synonyms: 4-((3R,5S)-2-oxo-5-phenyl-morpholin-3-yl)phenyl acetate
• CAS NO: 1327278-14-7
• Molecular Weight: 311.337
• Mol File: 1327278-14-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-((3R,5S)-2-oxo-5-phenyl-morpholin-3-yl)phenyl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: 4-((3R,5S)-2-oxo-5-phenyl-morpholin-3-yl)phenyl acetate(1327278-14-7)
• EPA Substance Registry System: 4-((3R,5S)-2-oxo-5-phenyl-morpholin-3-yl)phenyl acetate(1327278-14-7)

Safety Data

• Hazardous Substances Data: 1327278-14-7(Hazardous Substances Data)

Upstream product

• 38177-33-2 (4-acetoxyphenyl)acetic acid 
• 65448-20-6 4-acetoxyphenylacetyl chloride 
• 1327277-97-3 4-(((S)-2-hydroxy-1-phenylethylcarbamoyl)methyl)phenyl acetate 
• 1327278-09-0 4-((S)-5,6-dihydro-2-oxo-5-phenyl-2H-1,4-oxazin-3-yl)phenyl acetate 
• 1327278-02-3 4-(((S)-4,5-dihydro-4-phenyloxazol-2-yl)methyl)phenyl acetate 

Downstream Products

• 22818-40-2 D-4-hydroxyphenylglycine 
• 37763-23-8 D-2-p-hydroxyphenylglycine methyl ester 

Relevant articles and documents

Preparation of α-amino acids by oxidative oxazoline-oxazinone rearrangement-hydrogenation (OOOH). Scope and limitations

The range and scope of the oxidative oxazoline-oxazinone rearrangement-hydrogenation sequence (OOOH)-a short, direct asymmetric synthesis of α-amino acids from carboxylic acids-was explored. The highest yet reported diastereoselectivity for hydrogenation of the oxazinone C=N bond (d.r.=>80:1) is disclosed and rationalized with the aid of ab initio molecular calculations.