132776-59-1

Basic information

• Product Name: 3'-methoxyspecionin
• Synonyms: 3'-methoxyspecionin
• CAS NO: 132776-59-1
• Molecular Weight: 424.448
• Mol File: 132776-59-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3'-methoxyspecionin(CAS DataBase Reference)
• NIST Chemistry Reference: 3'-methoxyspecionin(132776-59-1)
• EPA Substance Registry System: 3'-methoxyspecionin(132776-59-1)

Safety Data

• Hazardous Substances Data: 132776-59-1(Hazardous Substances Data)

Upstream product

• 122-51-0 orthoformic acid triethyl ester 
• 75598-56-0 hexaacetyl-picroside-II 
• 132776-58-0 (1S,2S,6R,7S,8R,9S)-(-)-9-acetoxymethyl-7-(acetylvanilloyloxy)-8,9-epoxy-2-ethoxy-3-oxabicyclo<4.3.0>non-4-ene 
• 132776-57-9 10,4'-O-diacetyl-3'-methoxyspecionin 

Relevant articles and documents

Chemistry and Stereochemistry of Iridoids XV. - An Efficient Synthesis of Enantiomerically Pure (-)-Specionin Analogs from Peracetylated Iridoid Glucosides. - Crystal and Molecular Structure of (-)-3'-Methoxyspecionin

When peracetylated iridoid glucosides are submitted to hydroxymercuration and reduction with zinc the glucoside bond is cleaved exclusively.The aglycones can be regio- and stereoselectively transformed into specionin analogs.An example is the preparation