132840-93-8

Basic information

• Product Name: (R)-1-[2-((2S,3R,4S,5R,6R)-3,4,5-Trimethoxy-6-methoxymethyl-tetrahydro-pyran-2-yloxy)-cyclohexa-2,5-dienyl]-propan-2-ol
• CAS NO: 132840-93-8
• Molecular Weight: 372.459
• Mol File: 132840-93-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (R)-1-[2-((2S,3R,4S,5R,6R)-3,4,5-Trimethoxy-6-methoxymethyl-tetrahydro-pyran-2-yloxy)-cyclohexa-2,5-dienyl]-propan-2-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-1-[2-((2S,3R,4S,5R,6R)-3,4,5-Trimethoxy-6-methoxymethyl-tetrahydro-pyran-2-yloxy)-cyclohexa-2,5-dienyl]-propan-2-ol(132840-93-8)
• EPA Substance Registry System: (R)-1-[2-((2S,3R,4S,5R,6R)-3,4,5-Trimethoxy-6-methoxymethyl-tetrahydro-pyran-2-yloxy)-cyclohexa-2,5-dienyl]-propan-2-ol(132840-93-8)

Safety Data

• Hazardous Substances Data: 132840-93-8(Hazardous Substances Data)

Upstream product

• 3149-60-8 phenyl per-O-methyl-β-D-glucopyranoside 
• 1464-44-4 phenyl-β-D-glucopyranoside 
• 115431-90-8 1-(per-O-methyl-β-D-glucopyranosyloxy)-1,4-cyclohexadiene 
• 15448-47-2 (R)-propylene oxide 
• 16088-62-3 (S)-Propylene oxide 

Relevant articles and documents

REGIO- AND STEREOSELECTIVE CONTROL IN THE ALKYLATION OF 1-ALKOXY-1,4-CYCLOHEXADIENES BY THE CHIRAL AUXILIARY APPROACH. ENANTIOSELECTIVE SYNTHESIS OF PRECURSORS FOR CIS-HYDRINDANES.

A method is described for the regio- and diastereoselective alkylation of optically active 1-alkoxy-1,4-cyclohexadienes.Reaction conditions were optimised for substrates 4a with the per-O-methyl-β-D-glucopyranosyl group as chiral auxiliary.In the methylat