1330147-11-9Relevant articles and documents
DDQ-promoted dehydrogenation from natural rigid polycyclic acids or flexible alkyl acids to generate lactones by a radical ion mechanism
Ding, Ye,Huang, Zhangjian,Yin, Jian,Lai, Yisheng,Zhang, Shibo,Zhang, Zhiguo,Fang, Lei,Peng, Sixun,Zhang, Yihua
, p. 9495 - 9497 (2011)
A novel and facile DDQ-mediated dehydrogenation from natural rigid polycyclic acids or flexible alkyl acids to generate lactones is described. The formation of lactones proceeds by a radical ion mechanism, which has been established by DPPH?-mediated chemical identification, ESR spectroscopy and an enol intermediate trapping.