13302-06-2 Usage
General Description
Tributylstannyl methanesulfonate is an organotin compound containing a stannyl group and a methanesulfonate group. It is commonly used as a reagent in organic synthesis, particularly in the field of organotin chemistry. This chemical is known for its ability to facilitate carbon-carbon bond formation, as well as for its use in various coupling reactions. However,
Check Digit Verification of cas no
The CAS Registry Mumber 13302-06-2 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,3,3,0 and 2 respectively; the second part has 2 digits, 0 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 13302-06:
(7*1)+(6*3)+(5*3)+(4*0)+(3*2)+(2*0)+(1*6)=52
52 % 10 = 2
So 13302-06-2 is a valid CAS Registry Number.
InChI:InChI=1/3C4H9.CH4O3S.Sn/c3*1-3-4-2;1-5(2,3)4;/h3*1,3-4H2,2H3;1H3,(H,2,3,4);/rC12H27Sn.CH4O3S/c1-4-7-10-13(11-8-5-2)12-9-6-3;1-5(2,3)4/h4-12H2,1-3H3;1H3,(H,2,3,4)
13302-06-2Relevant articles and documents
Synthesis and spectral characterization of medium ring distannacycloalkanes and their Lewis acid derivatives
Farah, Dan,Swami, Kamal,Kuivila, Henry G.
, p. 311 - 334 (1992)
A study of the syntheses and some properties of several methyl substituted acyclic and cyclic bidentate organotin Lewis acids has been carried out.Of particular interest were cyclic species with 7-, 8-, 9- and 10-membered rings.The distannalkanes and distannacycloalkanes were converted to the chlorides by chlorodemethylation with tin chlorides or mercuric chloride; this reaction was accompanied by ring cleavage in some cases.Chlorides, in turn, were readily converted to the methanesulfonates and trifluoromethanesulfonates. 1H, 13C and 119Sn NMR and IR spectral data were used to gain information concerning structures, conformations and aggregation behavior.The mesylates are associated in chloroform; the triflates are not.
