133191-78-3Relevant articles and documents
Chemical synthesis of β-homonojirimycin, of its N-butyl derivative, and of 'methyl homoazacellobioside'
Saavedra,Martin
, p. 6987 - 6993 (2007/10/03)
β-Homonojirimycin (2) was prepared by the highly stereoselective double reductive amination of a 2,6-heptodiulose derivative (6 or 13) using ammonium formate and NaBH3CN. The process was unsuccessful with primary amines. The synthesis of N-buty
Conversion of D-Glucose to L-Glucose: Oxidative Decarboxylation of α-Oxy Carboxylic Acids via Their Diacyl Peroxides
Shiozaki, Masao
, p. 528 - 532 (2007/10/02)
D-Glucose was converted to an L-glucose derivative.The key step was the oxidative decarboxylation of carboxylic acid 12 via its diacyl peroxide derivative.This synthetic scheme proceeds through C-glycosidic compounds and is applicable to other sugar confi