1333398-11-0

Basic information

• Product Name: (1R,2S)-2-methyl-indane-1,2-epoxide
• CAS NO: 1333398-11-0
• Molecular Weight: 146.189
• Mol File: 1333398-11-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (1R,2S)-2-methyl-indane-1,2-epoxide(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2S)-2-methyl-indane-1,2-epoxide(1333398-11-0)
• EPA Substance Registry System: (1R,2S)-2-methyl-indane-1,2-epoxide(1333398-11-0)

Safety Data

• Hazardous Substances Data: 1333398-11-0(Hazardous Substances Data)

Upstream product

• 2177-47-1 2-Methylindene 

Relevant articles and documents

New mannose-derived ketones as organocatalysts for enantioselective dioxirane-mediated epoxidation of arylalkenes. Part 3: Chiral ketones from sugars

New d-arabino-hexopyranosid-3-uloses were synthesized by a simple method from mannopyranoside derivatives. The common skeleton possesses a tunable alkoxy group as steric sensor on carbon 2 of the sugar. The new ketones were employed in the dioxirane-mediated epoxidation of a range of trans- and trisubstituted arylalkenes giving enantiomeric excesses from low to good (30-90%). The effect of the size of the steric sensor on the enantioselectivity was also studied. The least bulky group (methoxy group) enhanced the stereoselectivity (up to 90% ee toward triphenylethylene).