133473-26-4

Basic information

• Product Name: 3-(2-NITRO-PHENYL)-PROPIONALDEHYDE
• Synonyms: 3-(2-NITRO-PHENYL)-PROPIONALDEHYDE;Benzenepropanal, 2-nitro-;3-(2-nitrophenyl)propanal
• CAS NO: 133473-26-4
• Molecular Formula: C₉H₉NO₃
• Molecular Weight: 179.17266
• Mol File: 133473-26-4.mol
• Article Data: 13

Chemical Properties

• Boiling Point: 283.292°C at 760 mmHg
• Flash Point: 128.296°C
• Appearance: /
• Density: 1.211g/cm³
• Vapor Pressure: 0.003mmHg at 25°C
• Refractive Index: 1.551
• CAS DataBase Reference: 3-(2-NITRO-PHENYL)-PROPIONALDEHYDE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(2-NITRO-PHENYL)-PROPIONALDEHYDE(133473-26-4)
• EPA Substance Registry System: 3-(2-NITRO-PHENYL)-PROPIONALDEHYDE(133473-26-4)

Safety Data

• Hazardous Substances Data: 133473-26-4(Hazardous Substances Data)

Usage

InChI:InChI=1/C9H9NO3/c11-7-3-5-8-4-1-2-6-9(8)10(12)13/h1-2,4,6-7H,3,5H2

Upstream product

• 1466-88-2 2-nitrocinnamic aldehyde 
• 1466-88-2 2-nitrocinnamaldehyde 
• 609-73-4 o-nitroiodobenzene 
• 107-18-6 allyl alcohol 
• 1504-65-0 3-(2-nitrophenyl)prop-2-en-1-ol 
• 24393-59-7 (E)-ethyl 3-(2-nitrophenyl)acrylate 
• 15121-84-3 2-nitro-benzeneethanol 
• 20716-26-1 3-(2-nitro-phenyl)-propan-1-ol 
• 2437-05-0 ethyl 3-(2-nitrophenyl)acrylate 
• 114446-46-7 1-<<3-(o-Nitrophenyl)propyl>oxy>-2-methyl-9,10-anthraquinone 
• 133473-25-3 o-(3-iodopropyl)nitrobenzene 
• 274676-13-0 methyl (+/-)-2-(2-nitrophenyl)-4-pentenoate 
• 30095-98-8 methyl (2-nitrophenyl)acetate 
• 102330-20-1 1-(but-3-en-1-yl)-2-nitrobenzene 

Downstream Products

• 1119238-24-2 (R)-1,2,3,4-tetrahydroquinolin-3-ol 
• 1030620-43-9 2,2-dimethyl-5-[3-(2-nitrophenyl)propyl][1,3]dioxane-4,6-dione 
• 1619998-87-6 methyl 2-methylene-5-(2-nitrophenyl)pentanoate 
• 1466-88-2 2-nitrocinnamic aldehyde 
• 1333149-78-2 (R)-3-(2-nitrophenyl)-2-(9H-xanthen-9-yl)propanal 
• 1351511-30-2 (E)-N-(2-(hexa-3,5-dien-1-yl)phenyl)-4-methoxybenzenesulfonamide 
• 1351511-79-9 (E)-2-(hexa-3,5-dien-1-yl)aniline 
• 1351511-57-3 (E)-1-((4-methoxyphenyl)sulfonyl)-2-(prop-1-en-1-yl)-1,2,3,4-tetrahydroquinoline 
• 1351511-43-7 C₁₉H₂₁NO₃S 

Relevant articles and documents

Photodemethylation of Methoxy-Substituted 9,10-Anthraquinones in Methanol

Irradiation of methoxy-substituted 9,10-anthraquinones with visible or ultraviolet light results in a demethylation reaction involving free radical intermediates.

CoPd Nanoalloys with Metal–Organic Framework as Template for Both N-Doped Carbon and Cobalt Precursor: Efficient and Robust Catalysts for Hydrogenation Reactions

In this work, a series of metal–organic framework (MOF)-derived CoPd nanoalloys have been prepared. The nanocatalysts exhibited excellent activities in the hydrogenation of nitroarenes and alkenes in green solvent (ethanol/water) under mild conditions (H2 balloon, room temperature). Using ZIF-67 as template for both carbon matrix and cobalt precursor coating with a mesoporous SiO2 layer, the catalyst CoPd/NC@SiO2 was smoothly constructed. Catalytic results revealed a synergistic effect between Co and Pd components in the hydrogenation process due to the enhanced electron density. The mesoporous SiO2 shell effectively prevented the sintering of hollow carbon and metal NPs at high temperature, furnishing the well-dispersed nanoalloy catalysts and better catalytic performance. Moreover, the catalyst was durable and showed negligible activity decay in recycling and scale-up experiments, providing a mild and highly efficient way to access amines and arenes.

Process for Synthesis of Chiral 3-Substituted Tetrahydroquinoline Derivatives

The present invention relates to novel and concise process for the construction of chiral 3-substituted tetrahyroquinoline derivatives based on proline catalyzed asymmetric α-functionalization of aldehyde, followed by in situ reductive cyclization of nitro group under catalytic hydrogenation condition with high optical purities. Further the invention relates to conversion of derived chiral 3-substituted tetrahydroquinoline derivatives into therapeutic agents namely (?)-sumanirole (96% ee) and 1-[(S)-3-(di-methylamino)-3,4-dihydro-6,7-dimethoxy-quinolin-1(2H)-yl]propanone[(S)-903] (92% ee).