13351-86-5Relevant articles and documents
Cobalt-mediated radical polymerization routes to poly(vinyl ester) block copolymers
Bunck, David N.,Sorenson, Gregory P.,Mahanthappa, Mahesh K.
, p. 242 - 249 (2011)
Cobalt-mediated radical polymerizations (CMRPs) utilizing redox initiation are demonstrated to produce poly(vinyl ester) homopolymers derived from vinyl pivalate (VPv) and vinyl benzoate (VBz), and their block copolymers with vinyl acetate (VAc). Combinin
Synthesis of α-Amidoketones from Vinyl Esters via a Catalytic/Thermal Cascade Reaction
Holthusen, Katharina,Leitner, Walter,Franciò, Giancarlo
, p. 4823 - 4828 (2016/07/06)
A straightforward, modular, and atom-efficient method is reported for the synthesis of α-amidoketones from vinyl esters via a cascade reaction including hydroformylation, condensation with a primary amine, and a rearrangement step giving water as the only byproduct. The reaction sequence can be performed in one pot or as a three-step procedure. The synthetic applicability is demonstrated by the preparation of different α-amidoketones in moderate to good yields.
An expedient biocatalytic procedure for abasic site precursors useful in oligonucleotide synthesis
Martinez-Montero, Saul,Fernandez, Susana,Sanghvi, Yogesh S.,Gotor, Vicente,Ferrero, Miguel
experimental part, p. 5960 - 5966 (2011/10/05)
Preparation of abasic site precursors through a divergent chemoenzymatic synthesis has been accomplished. Several biocatalysts and acylating agents were studied furnishing a practical and scalable green method useful for industrial applications. Highly re