133620-92-5

Basic information

• Product Name: (6-Bromo-4-methoxy-2-methylene-hexylsulfanyl)-benzene
• Synonyms: (6-Bromo-4-methoxy-2-methylene-hexylsulfanyl)-benzene
• CAS NO: 133620-92-5
• Molecular Weight: 315.274
• Mol File: 133620-92-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (6-Bromo-4-methoxy-2-methylene-hexylsulfanyl)-benzene(CAS DataBase Reference)
• NIST Chemistry Reference: (6-Bromo-4-methoxy-2-methylene-hexylsulfanyl)-benzene(133620-92-5)
• EPA Substance Registry System: (6-Bromo-4-methoxy-2-methylene-hexylsulfanyl)-benzene(133620-92-5)

Safety Data

• Hazardous Substances Data: 133620-92-5(Hazardous Substances Data)

Upstream product

• 36255-44-4 3-bromopropanal dimethyl acetal 
• 116279-69-7 <2-<(phenylthio)methyl>allyl>trimethylsilane 

Downstream Products

• 59627-58-6 3-methylenecyclohexyl methyl ether 

Relevant articles and documents

[3+3] Annulation by sequential two electron and one electron allylation

3-phenylthio-2-(trimethylsilymethyl)propene is a convenient conjunctive reagent for the preparation of methylenecyclohexanes via a [3+3] annulation. The trimethylsilyl group facilitates the Lewis acid catalyzed allylation of an aldehyde or acetal while the phenylthio group directs a 6-endo-trig radical cyclization reaction.