133752-75-7

Basic information

• Product Name: 2,3,4,5-Tetrachlor-6-(3-methoxypropoxy)phenol
• Synonyms: 2,3,4,5-Tetrachlor-6-(3-methoxypropoxy)phenol
• CAS NO: 133752-75-7
• Molecular Weight: 320
• Mol File: 133752-75-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 2,3,4,5-Tetrachlor-6-(3-methoxypropoxy)phenol(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3,4,5-Tetrachlor-6-(3-methoxypropoxy)phenol(133752-75-7)
• EPA Substance Registry System: 2,3,4,5-Tetrachlor-6-(3-methoxypropoxy)phenol(133752-75-7)

Safety Data

• Hazardous Substances Data: 133752-75-7(Hazardous Substances Data)

Upstream product

• 503-30-0 trimethylene oxide 
• 67-56-1 methanol 
• 31680-14-5 Tetrachlor-1,2-benzochinondiazid 

Relevant articles and documents

Crown Ethers from o-Quinone Diazides and Oxetane

The carbenes 11, generated by photolysis of the di- and tetrachloro-o-quinone diazides 10, react with oxetane in a 1:3 ratio to give the 15-membered crown ethers 19.In the presence of methanol, the oxonium ions 12 are trapped with formation of 1-(aryloxy)-3-methoxypropanes (13).In the absence of additional nucleophiles, 12 react with oxetane until the chain length is appropriate for inverting intramolecular attack of the aryl oxide at the α-carbon atom of the oxonium ion (18 -> 19). Key Words: Carbonyl carbenes/ Oxygen ylides/ Displacement, nucleophilic, intramolecular/ Carbenes/ Ylides