1338468-26-0

Basic information

• Product Name: methyl 5-((1'S,2'R)-2-(benzyl(tert-butoxycarbonyl)amino)-1'-formylcyclohex-3'-enyl)pentanoate
• Synonyms: methyl 5-((1'S,2'R)-2-(benzyl(tert-butoxycarbonyl)amino)-1'-formylcyclohex-3'-enyl)pentanoate
• CAS NO: 1338468-26-0
• Molecular Weight: 429.557
• Mol File: 1338468-26-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl 5-((1'S,2'R)-2-(benzyl(tert-butoxycarbonyl)amino)-1'-formylcyclohex-3'-enyl)pentanoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 5-((1'S,2'R)-2-(benzyl(tert-butoxycarbonyl)amino)-1'-formylcyclohex-3'-enyl)pentanoate(1338468-26-0)
• EPA Substance Registry System: methyl 5-((1'S,2'R)-2-(benzyl(tert-butoxycarbonyl)amino)-1'-formylcyclohex-3'-enyl)pentanoate(1338468-26-0)

Safety Data

• Hazardous Substances Data: 1338468-26-0(Hazardous Substances Data)

Upstream product

• 1338468-13-5 methyl 6-formyl-6-eneoate 
• 1338468-23-7 (E)-tert-butyl benzyl(3-oxobut-1-en-1-yl)carbamate 
• 1338468-24-8 tert-butyl N-benzyl-N-[(E)-3-hydroxybut-1-enyl]carbamate 
• 35376-00-2 methyl 7-oxoheptanoate 
• 628-92-2 Cycloheptene 
• 100-46-9 benzylamine 
• 187606-80-0 (E)-4-(benzylamino)but-3-en-2-one 

Downstream Products

• 1338468-29-3 (2S,6S,7R)-methyl 7-(benzyl(tert-butoxycarbonyl)amino)-1-oxospiro[5.5]undec-8-ene-2-carboxylate 
• 1338468-28-2 (1R,4R,9S)-methyl-3-benzyl-13-oxo-3-azatricyclotridec[8.3.1.0(4,9)]-5-ene-1-carboxylate 
• 1338468-30-6 (1R,4R,9S,13S)-methyl 3-benzyl-13-hydroxy-3-azatricyclotridec[8.3.1.0(4,9)]-5-ene-1-carboxylate 
• 1338468-31-7 C₂₁H₂₅NO₃ 

Relevant articles and documents

The enantioselective synthesis of tetracyclic methyllycaconitine analogues

A new enantioselective synthesis of ABEF ring analogues of methyllycaconitine has been developed using a chiral cobalt(III) salen-catalyzed Diels-Alder reaction to form the B ring. Subsequent elaboration to form the A, E and F rings was achieved by sequential Dieckmann, Mannich and Wacker-type cyclizations to afford tetracyclic analogues in 97.5% ee.