13392-51-3Relevant articles and documents
Transesterification of trialkyl phosphates from alkyl bromides
Lherbet, Christian,Castonguay, Roselyne,Keillor, Jeffrey W.
, p. 3565 - 3567 (2005)
The treatment of trialkyl phosphate with different alkyl bromides provides facile access to mixed phosphate esters. The presence of substoichiometric amounts of lithium bromide was found to be critical to this transesterification process, supporting a mechanism involving initial generation of phosphate anion, followed by its nucleophilic attack on alkyl bromide.
Aroyl group driven [1,2] phosphonate-phosphate/phosphine oxide-phosphinate rearrangement
Khan, Shahnawaz,Battula, Satyanarayana,Ahmed, Qazi Naveed
, p. 4273 - 4279 (2016/07/06)
Aroyl group driven phosphonate-phosphate rearrangement in dialkyl/aryl(α-hydroxy-β-oxo-β-arylethyl)phosphonates having α-proton under basic conditions is presented and extended to a novel one-pot direct coupling method between 2-oxoaldehydes (2OA) and H-p
DIMETHYLDIOXIRANE EPOXIDATION OF ENOL PHOSPHATES
Adam, Waldemar,Hadjiarapoglou, Lazaros,Klicic, Jasna
, p. 6517 - 6520 (2007/10/02)
The novel epoxides 2 of a variety of enol phosphates 1 were readily prepared by epoxidation with dimethyldioxirane at subambient temperatures; at room temperature these labile epoxides 2 rearranged into the corresponding α-dialkoxyphosphinyloxy-substitute
