134022-40-5Relevant articles and documents
A mild and efficient procedure for alkenols oxyselenocyclization by using ionic liquids
Kosti?, Marina,Verdía, Pedro,Fernández-Stefanuto, Verónica,Puchta, Ralph,Tojo, Emilia
supporting information, (2019/01/08)
A mild and efficient procedure for the oxyselenocyclization of unsaturated alcohols by treatment with phenylselenyl chloride using ionic liquids as solvents/catalyzers has been developed. The reaction proceeds instantaneously under mild conditions with ab
Regio- and stereoselectivity in phenylselenoetherification of (Z)- and (E)-hex-4-en-1-ols
Divac, Vera M.,Bugarcic, Zorica M.
experimental part, p. 3684 - 3688 (2010/03/25)
Δ4-Primary alkenols (Z)- and (E)-hex-4-en-l-ols underwent facile cyclization to the corresponding phenyl selenoethers using PhSeX (X = Cl, Br) in high yields and in good to excellent selectivities in the presence of some catalysts (Lewis acids
Molecular orbital study of the rearrangement of seleniranium ions
Markovic, Zoran,Konstantinovic, Stanimir,Juranic, Ivan,Dosen-Micovic, Ljiljana
, p. 429 - 434 (2007/10/03)
The mechanism of phenylselenoetherification of unsaturated alcohols, involving seleniranium cationic intermediates, is studied by the semiempirical molecular-orbital MNDO-PM3 method.Results of calculation on several Δ4-alkenols attacked by PhSe
