134022-56-3

Basic information

• Product Name: 1-phenylthio-1,1-bis(trimethylsilyl)-3-phenylpropane
• Synonyms: 1-phenylthio-1,1-bis(trimethylsilyl)-3-phenylpropane
• CAS NO: 134022-56-3
• Molecular Weight: 386.749
• Mol File: 134022-56-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-phenylthio-1,1-bis(trimethylsilyl)-3-phenylpropane(CAS DataBase Reference)
• NIST Chemistry Reference: 1-phenylthio-1,1-bis(trimethylsilyl)-3-phenylpropane(134022-56-3)
• EPA Substance Registry System: 1-phenylthio-1,1-bis(trimethylsilyl)-3-phenylpropane(134022-56-3)

Safety Data

• Hazardous Substances Data: 134022-56-3(Hazardous Substances Data)

Upstream product

• 637-59-2 1-Bromo-3-phenylpropane 
• 62761-90-4 α,α-bis(trimethylsilyl)methylphenyl sulfide 
• 17873-08-4 (phenylsulfanylmethyl)trimethylsilane 

Downstream Products

• 2046-17-5 methyl 3-(benzyl)propanoate 

Relevant articles and documents

New one carbon homologation reagents utilizing electrochemical oxidation of organosilicon compounds

Phenylthio(trimethylsilyl)methane, phenylthiobis(trimethylsilyl)methane, methoxy(trimethylsilyl)-methane, and methoxybis(trimethylsilyl)methane are deprotonated and the resulting anions are alkylated with electrophiles such as organic halides. The alkylation products are readily converted into the corresponding dimethyl acetals or methyl esters by electrochemical oxidation in methanol.