1341216-62-3

Basic information

• Product Name: (2R,3S)-2-methyl-2-(2-methylene-12-phenyldodecyl)-3-vinyloxirane
• Synonyms: (2R,3S)-2-methyl-2-(2-methylene-12-phenyldodecyl)-3-vinyloxirane
• CAS NO: 1341216-62-3
• Molecular Weight: 340.549
• Mol File: 1341216-62-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (2R,3S)-2-methyl-2-(2-methylene-12-phenyldodecyl)-3-vinyloxirane(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,3S)-2-methyl-2-(2-methylene-12-phenyldodecyl)-3-vinyloxirane(1341216-62-3)
• EPA Substance Registry System: (2R,3S)-2-methyl-2-(2-methylene-12-phenyldodecyl)-3-vinyloxirane(1341216-62-3)

Safety Data

• Hazardous Substances Data: 1341216-62-3(Hazardous Substances Data)

Upstream product

• 39598-55-5 (bromomethylene)triphenylphosphorane 
• 1341216-64-5 (2R)-2-(10-phenyldecyl)oxirane 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 1341216-70-3 methyl (2R,3R)-3-methyl-3-(2-methylene-12-phenyldodecyl)oxirane-2-carboxylate 
• 1341216-69-0 methyl (2R,3R)-3-methyl-3-(2-oxo-12-phenyldodecyl)oxirane-2-carboxylate 
• 1341216-66-7 (1R,4R,6R)-6-methyl-4-(10-phenyldecyl)-3,7-dioxabicyclo[4.1.0]heptan-2-one 
• 1341216-63-4 (R)-4-methyl-6-(10-phenyldecyl)-5,6-dihydro-2H-pyran-2-one 

Downstream Products

• 1341216-71-4 triethyl((2-methyl-1-((2R,3S)-2-methyl-3-vinyloxiran-2-yl)-12-phenyldodecan-2-yl)peroxy)silane 
• 1341216-72-5 (1S)-1-[(3R,5RS)-3,5-dimethyl-5-(10-phenyldecyl)-1,2-dioxolan-3-yl]prop-2-en-1-ol 
• 1341216-61-2 C₂₄H₃₈O₃ 

Relevant articles and documents

Asymmetric synthesis of andavadoic acid via base-catalyzed 5-exo-tet cyclization of a β-hydroperoxy epoxide

The first total synthesis of andavadoic acid, a naturally occurring five-membered ring peroxide, and its absolute configuration assignment are reported. Central to this venture was the development of an effective synthesis of a key β-hydroperoxy epoxy ester from (R)-epichlorohydrin via chemoselective methylenation with Nysted reagent in the presence of Ti(Oi-Pr)2Cl2 and chemo- and regioselective Mukaiyama-Isayama peroxidation. This approach also featured the construction of the 1,2-dioxolane ring system by an efficient base-promoted 5-exo epoxide opening by a hydroperoxy group.