1342864-93-0

Basic information

• Product Name: O-(2-formyl-6-methylphenyl) N,N-dimethylthiocarbamate
• Synonyms: O-(2-formyl-6-methylphenyl) N,N-dimethylthiocarbamate
• CAS NO: 1342864-93-0
• Molecular Weight: 223.296
• Mol File: 1342864-93-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: O-(2-formyl-6-methylphenyl) N,N-dimethylthiocarbamate(CAS DataBase Reference)
• NIST Chemistry Reference: O-(2-formyl-6-methylphenyl) N,N-dimethylthiocarbamate(1342864-93-0)
• EPA Substance Registry System: O-(2-formyl-6-methylphenyl) N,N-dimethylthiocarbamate(1342864-93-0)

Safety Data

• Hazardous Substances Data: 1342864-93-0(Hazardous Substances Data)

Upstream product

• 824-42-0 2-methoxy-3-methylbenzaldehyde 
• 16420-13-6 N,N-Dimethylthiocarbamoyl chloride 

Downstream Products

• 824-42-0 2-methoxy-3-methylbenzaldehyde 
• 1259480-34-6 C₈H₈OS 
• 1342865-02-4 S-(2-formyl-6-methylphenyl) N,N-dimethylthiocarbamate 
• 1342865-21-7 tris[2-(N,N-dimethylthiocarbamoyl)-3-methylbenzyl]amine 
• 1342865-30-8 tris(2-mercapto-3-methylbenzyl)amine 

Relevant articles and documents

Divergent Synthesis of Disulfanes and Benzenesulfonothioates Bearing 2-Aminofurans From N-Tosylhydrazone-Bearing Thiocarbamates

An efficient and convenient synthesis of valuable disulfanes and benzenesulfonothioates, having a 2-aminofuran framework, has been developed by employing a copper-catalyzed transformation of readily available N-tosylhydrazone-bearing thiocarbamates. This method features an inexpensive metal catalyst, mild reaction conditions, good functional-group tolerance, short reaction times, and delivers valuable and complex products. A copper carbene generated from an N-tosylhydrazone-bearing thiocarbamate is proposed as the key intermediate for the transformation and it triggers the subsequent cascade. Remarkably, the Ts anion released from N-tosylhydrazone further serves as a nucleophile, thus rendering the formation of benzenesulfonothioates under controlled conditions.