134287-14-2Relevant articles and documents
Flow Thermolysis Rearrangements in the Indole Alkaloid Series: 1,2-Dehydroaspidospermidine
Hugel, Georgette,Royer, Daniel,Sigaut, Francoise,Levy, Jean
, p. 4631 - 4636 (1991)
Flow thermolysis of 1,2-dehydroaspidospermidine (1) at various temperatures allowed isolation of all four predictable rearrangement products, namely indolenines 2 and 3 and indoles 4 and 5.The structures of the rearranged products were confirmed by chemical and spectroscopic means, particularly HMBC and HMQC NMR techniques.