13432-71-8

Basic information

• Product Name: 3,5-Dimethyl-1,4-benzoquinone 4-oxime
• Synonyms: 3,5-Dimethyl-1,4-benzoquinone 4-oxime
• CAS NO: 13432-71-8
• Molecular Weight: 151.165
• Mol File: 13432-71-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3,5-Dimethyl-1,4-benzoquinone 4-oxime(CAS DataBase Reference)
• NIST Chemistry Reference: 3,5-Dimethyl-1,4-benzoquinone 4-oxime(13432-71-8)
• EPA Substance Registry System: 3,5-Dimethyl-1,4-benzoquinone 4-oxime(13432-71-8)

Safety Data

• Hazardous Substances Data: 13432-71-8(Hazardous Substances Data)

Upstream product

• 108-68-9 3,5-Dimethylphenol 

Downstream Products

• 17302-62-4 3,5-Dimethyl-benzochinon-4-oximmethylether 
• 250725-09-8 C₁₅H₁₂N₂O₅ 
• 250725-10-1 C₁₄H₁₃NO₄S 
• 527-61-7 2,6-dimethyl-1,4-benzoquinone 
• 1243378-02-0 3,5-dimethyl-4-(phenylaminocarbonyloxyimino)cyclohexa-2,5-dien-1-one 
• 1243378-03-1 3,5-dimethyl-4-[(4-methylphenyl)aminocarbonyloxyimino]cyclohexa-2,5-dien-1-one 
• 1243378-04-2 4-[(3-chlorophenyl)aminocarbonyloxyimino]-3,5-dimethylcyclohexa-2,5-dien-1-one 
• 14102-24-0 3,5-Dimethyl-N-p-tolylsulfonyl-1,4-benzoquinonimine 
• 14034-16-3 N-(4-hydroxy-2,6-dimethylphenyl)-4-methylbenzenesulfonamide 
• 3096-70-6 3,5-dimethyl-4-aminophenol 

Relevant articles and documents

The Diels-Alder reactions of para-benzoquinone nitrogen-derivatives: An experimental and theoretical study

An experimental and theoretical study of the comparative reactivity and selectivity of the Diels-Alder reactions of para-benzoquinones and three nitrogen derivatives have been performed. The mono-oximes derivatives do not react under the tested reaction conditions, whereas the tosylated mono-oximes react slowly. However, the mono N-tosyl imines show excellent reactivity, and superior to the parent parabenzoquinones. DFT calculations support these experimental results.