134450-66-1

Basic information

• Product Name: 9-phenyl-10-nitroanthracene
• Synonyms: 9-phenyl-10-nitroanthracene
• CAS NO: 134450-66-1
• Molecular Weight: 299.329
• Mol File: 134450-66-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 9-phenyl-10-nitroanthracene(CAS DataBase Reference)
• NIST Chemistry Reference: 9-phenyl-10-nitroanthracene(134450-66-1)
• EPA Substance Registry System: 9-phenyl-10-nitroanthracene(134450-66-1)

Safety Data

• Hazardous Substances Data: 134450-66-1(Hazardous Substances Data)

Upstream product

• 602-55-1 9-phenylanthracene 
• 7697-37-2 nitric acid 
• 64-19-7 acetic acid 
• 5336-95-8 N–nitrosuccinimide 

Downstream Products

• 4708-42-3 <10-Phenyl-anthryl-(9)>-<10-imino-9-phenyl-9,10-dihydro-anthryl-(9)>-amin 
• 96176-05-5 10-Benzoyloxy-10-phenyl-anthron-⁽⁹⁾ 
• 96176-28-2 Imid des 10-Benzoyloxy-10-phenyl-anthrons-⁽⁹⁾ 
• 5146-30-5 10-phenyl-10-hydroxy-9-anthracenone 
• 84-65-1 9,10-phenanthrenequinone 
• 1718-54-3 amino-9 phenyl-10 anthracene 

Relevant articles and documents

Succinimidylation and nitration of aromatic compounds by photolysis with N-nitrosuccinimide

N-Nitrosuccinimide (S-NO2) engages in weak charge transfer complexes with aromatic compounds (ArH).Upon photolysis with light of λ > 345 nm in dichloromethane, electron transfer within the charge transfer complex leads to the triad -NO2>from which products of eventual succinimidylation and/or nitration develop by initial attack of succinimide anion upon the radical cation.Photolysis in the presence of trifluoroacetic acid (0.4 mol dm-3) causes inactivation of S- by protonation, making EPR detection of ArH-radical cations or radicals cations formed by its further transformations possible.In acetonitrile, trifluoroacetic acid is too weak effectively to protonate S-, whereas addition of stronger acids again leads to the development of EPR spectra of ArH-radical cation in the case of 9,10-dimethylanthracene, the intensity increasing with decreasing pK of the acid.An X-ray crystal structure is reported for N-nitrosuccinimide.