1344716-76-2

Basic information

• Product Name: ethyl 4-[(3-methylphenyl)(phenyl)amino]benzoate
• Synonyms: ethyl 4-[(3-methylphenyl)(phenyl)amino]benzoate
• CAS NO: 1344716-76-2
• Molecular Weight: 331.414
• Mol File: 1344716-76-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: ethyl 4-[(3-methylphenyl)(phenyl)amino]benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 4-[(3-methylphenyl)(phenyl)amino]benzoate(1344716-76-2)
• EPA Substance Registry System: ethyl 4-[(3-methylphenyl)(phenyl)amino]benzoate(1344716-76-2)

Safety Data

• Hazardous Substances Data: 1344716-76-2(Hazardous Substances Data)

Upstream product

• 108-94-1 cyclohexanone 
• 108-44-1 1-amino-3-methylbenzene 
• 1205-64-7 3-Methyldiphenylamine 
• 17159-79-4 ethyl 4-oxocyclohexane-1-carboxylate 
• 5798-75-4 Ethyl 4-bromobenzoate 

Downstream Products

• 1344716-75-1 4-[(3-methylphenyl)(phenyl)amino]benzoic acid 

Relevant articles and documents

Synthesis of unsymmetrically substituted triarylaminesviaacceptorless dehydrogenative aromatization using a Pd/C andp-toluenesulfonic acid hybrid relay catalyst

An efficient and convenient procedure for synthesizing triarylamines based on a dehydrogenative aromatization strategy has been developed. A hybrid relay catalyst comprising carbon-supported Pd (Pd/C) andp-toluenesulfonic acid (TsOH) was found to be effective for synthesizing a variety of triarylamines bearing different aryl groups starting from arylamines (diarylamines or anilines), using cyclohexanones as the arylation sources under acceptorless conditions with the release of gaseous H2. The proposed reaction comprises the following relay steps: condensation of arylamines and cyclohexanones to produce imines or enamines, dehydrogenative aromatization of the imines or enamines over Pd nanoparticles (NPs), and elimination of H2from the Pd NPs. In this study, an interesting finding was obtained indicating that TsOH may promote the dehydrogenation.