134538-53-7

Basic information

• Product Name: 1,2,3-trimethoxy-5-(2-nitrobut-1-enyl)benzene
• Synonyms: 1,2,3-trimethoxy-5-(2-nitrobut-1-enyl)benzene
• CAS NO: 134538-53-7
• Molecular Weight: 267.282
• Mol File: 134538-53-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1,2,3-trimethoxy-5-(2-nitrobut-1-enyl)benzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,2,3-trimethoxy-5-(2-nitrobut-1-enyl)benzene(134538-53-7)
• EPA Substance Registry System: 1,2,3-trimethoxy-5-(2-nitrobut-1-enyl)benzene(134538-53-7)

Safety Data

• Hazardous Substances Data: 134538-53-7(Hazardous Substances Data)

Upstream product

• 92157-16-9 1-(3,4,5-trimethoxyphenyl)-2-butanone 
• 86-81-7 3,4,5-trimethoxy-benzaldehyde 
• 108-03-2 1-Nitropropane 

Relevant articles and documents

Palladium-catalyzed synthesis of substituted nitroolefins

A one-pot protocol toward several substituted nitroolefins 4 and 6 starting with substituted acetones 2 and 5 was described. A facile process was carried out for the triflation of substituted acetones 2 and 5 with triflic anhydride (Tf2O) under the basic condition (Cs2CO3) and then palladium-catalyzed cross-coupling of enol triflates 3 with NaNO 2 and BINAP in the presence of phase-transfer reagents (n-Bu 4NBr) under the refluxing 1,2-dimethoxyethane (DME) in acceptable yields.