1345836-60-3Relevant articles and documents
Rh-catalyzed asymmetric hydroformylation of functionalized 1,1-disubstituted olefins
Wang, Xiao,Buchwald, Stephen L.
, p. 19080 - 19083 (2012/01/05)
The first method for the highly enantioselective rhodium-catalyzed hydroformylation of 1,1-disubstituted olefins has been developed. By employing either of the P-chirogenic phosphine ligands BenzP* and QuinoxP*, linear aldehydes with β-chirality can be prepared in a highly enantioselective fashion with good chemo- and regioselectivities.