1345857-81-9

Basic information

• Product Name: methyl 3-(3,8-dibutyl-6-(trimethylsilyl)pyren-1-yl)benzoate
• Synonyms: methyl 3-(3,8-dibutyl-6-(trimethylsilyl)pyren-1-yl)benzoate
• CAS NO: 1345857-81-9
• Molecular Weight: 520.787
• Mol File: 1345857-81-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl 3-(3,8-dibutyl-6-(trimethylsilyl)pyren-1-yl)benzoate(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 3-(3,8-dibutyl-6-(trimethylsilyl)pyren-1-yl)benzoate(1345857-81-9)
• EPA Substance Registry System: methyl 3-(3,8-dibutyl-6-(trimethylsilyl)pyren-1-yl)benzoate(1345857-81-9)

Safety Data

• Hazardous Substances Data: 1345857-81-9(Hazardous Substances Data)

Upstream product

• 129-00-0 pyrene 
• 1345858-53-8 1,6-dibromo-3,8-dibutylpyrene 
• 1345857-75-1 (6-bromo-3,8-dibutylpyren-1-yl)trimethylsilane 
• 99769-19-4 [3-(methoxycarbonyl)phenyl]boronic acid 
• 1398505-94-6 1,6-dibutylpyrene 
• 27973-29-1 1,6-dibromopyrene 

Relevant articles and documents

Synthesis of unsymmetrically substituted pyrene derivatives through (6-bromo-3,8-dibutylpyren-1-yl)trimethylsilane

A straightforward route to unsymmetrically functionalized pyrene derivatives is described involving the synthesis of key precursor (6-bromo-3,8-dibutylpyren-1-yl)trimethylsilane 1. In a first step bromide 1 was successful in Suzuki-Miyaura, Sonogashira, and Buchwald-Hartwig cross-coupling reactions. Subsequent transformation of the trimethylsilyl group to bromide enabled the introduction of a second variable functional group onto the pyrene skeleton.