13459-17-1Relevant articles and documents
Photoinduced intramolecular hydrogen atom transfer in 2-(2-hydroxyphenyl)benzoxazole and 2-(2-hydroxyphenyl)benzothiazole studied by laser flash photolysis
Ikegami, Masashi,Arai, Tatsuo
, p. 1296 - 1301 (2002)
2-(2-Hydroxyphenyl)benzoxazole (HBO) and 2-(2-hydroxyphenyl)benzothiazole (HBT) underwent hydrogen atom transfer to give the tautomer in both the singlet excited state and the triplet excited state. In the singlet excited state, the keto form produced by excited state hydrogen atom transfer underwent isomerization around the quasi-double bond to give the trans-keto form. In the triplet excited state, HBO and HBT were equilibrated between the enol form and the cis-keto form and the equilibrium constant was determined by triplet sensitization and quenching experiment by using laser flash photolysis in benzene at room temperature. From these results, we have revealed the energy diagram of the hydrogen atom transfer reaction of HBO and HBT both in the singlet excited state and the triplet excited state.
Solvent-dependent photoinduced tautomerization of 2-(2′-hydroxyphenyl)benzoxazole
Abou-Zied, Osama K.,Jimenez, Ralph,Thompson, Elizabeth H.Z.,Millar, David P.,Romesberg, Floyd E.
, p. 3665 - 3672 (2002)
The solvent-dependent ground-state conformational equilibrium and excited-state dynamics of 2-(2′-hydroxyphenyl)benzoxazole have been characterized in several solvents on the femtosecond to nanosecond time scales. The only observable ground-state tautomer
TEMPO-mediated aerobic oxidative synthesis of 2-aryl benzoxazoles via ring-opening of benzoxazoles with benzylamines
Rao, Mugada Sugunakara,Hussain, Sahid
, p. 2684 - 2694 (2021/07/26)
A simple and efficient TEMPO-mediated system for aerobic oxidative synthesis of 2-aryl benzoxazoles from readily available benzoxazoles and primary benzylic and hetero benzylic amines is presented in one pot. The reaction proceeds through the ring-opening of benzoxazoles and is followed by oxidative condensation with benzylamines. These metal-free, straightforward reactions worked well with a wide range of substrates, yielding moderate to good yields under mild conditions using air as an external green oxidant.
Dowex 50W: A green mild reusable catalyst for the synthesis of 2-aryl benzoxazole derivatives in aqueous medium
Datta, Arup
, p. 341 - 347 (2021/05/19)
In this work simple efficient, one pot and environmentally friendly method was developed for the synthesis of 2-Aryl-1H-benzoxazole derivatives at 80oC using ortho-aminophenol and various aldehydes. It has been found that Dowex 50W is an effective catalyst to prepare moderate to high yield of a variety of benzoxazole derivatives through a clean and simple process. Aqueous medium, green methodology, rapid reaction, reusability of heterogeneous catalyst are the great advantages of this protocol.