134832-67-0

Basic information

• Product Name: sodium β-(N-p-tolylthiocarbamyl)thiocarbazinate
• Synonyms: sodium β-(N-p-tolylthiocarbamyl)thiocarbazinate
• CAS NO: 134832-67-0
• Molecular Weight: 263.32
• Mol File: 134832-67-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: sodium β-(N-p-tolylthiocarbamyl)thiocarbazinate(CAS DataBase Reference)
• NIST Chemistry Reference: sodium β-(N-p-tolylthiocarbamyl)thiocarbazinate(134832-67-0)
• EPA Substance Registry System: sodium β-(N-p-tolylthiocarbamyl)thiocarbazinate(134832-67-0)

Safety Data

• Hazardous Substances Data: 134832-67-0(Hazardous Substances Data)

Upstream product

• 463-58-1 carbon oxide sulfide 
• 13278-67-6 4-(4-methylphenyl)-3-thiosemicarbazide 

Downstream Products

• 134832-77-2 3-benzylmercapto-4(p-tolyl)-1,2,4-triazolin-5-one 
• 134832-72-7 2-(benzylthio)-5-(4-methylanilino)-1,3,4-oxadiazole 

Relevant articles and documents

Carbon oxysulphide: A novel reagent for the synthesis of 4-amino/anilino-3-aryl/aryloxymethyl/thiophenoxymethyl-1,2,4-triazolin-5-ones and 5-arylamino-2-mercapto-1,3,4-oxadiazoles

Acid hydrazides 1 on reaction with carbon oxysulphide in the presence of alcoholic KOH afford potassium β-acylthiocarbazinates 2 which on further reaction with hydrazine hydrate or phenylhydrazine give 4-amino-3-substituted-1,2,4-triazolin-5-ones 3 and 4-amilino-3-substituted-1,2,4-triazolin-5-ones 5 respectively. 4-Substituted thiosemicarbazides 6 on treatment with carbon oxysulphide in the presence of ale NaOH afford sodium β-(N-arylthiocarbamyl)thiocarbazinates 7 which on cyclisation in the presence of ethanolic NaOH afford 5-arylamino-2-mercapto-1,3,4-oxadiazoles 8. On reaction with benzyl chloride in the presence of NaOH 8 isomerise to 3-benzylmercapto-4-substituted-1,2,4-triazolin-5-ones 9.