13501-17-2

Basic information

• Product Name: (Z)-4-benzo[1,3,2]dioxaborol-2-yloxy-pent-3-en-2-one
• CAS NO: 13501-17-2
• Molecular Weight: 218.017
• Mol File: 13501-17-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (Z)-4-benzo[1,3,2]dioxaborol-2-yloxy-pent-3-en-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (Z)-4-benzo[1,3,2]dioxaborol-2-yloxy-pent-3-en-2-one(13501-17-2)
• EPA Substance Registry System: (Z)-4-benzo[1,3,2]dioxaborol-2-yloxy-pent-3-en-2-one(13501-17-2)

Safety Data

• Hazardous Substances Data: 13501-17-2(Hazardous Substances Data)

Upstream product

• 131276-97-6 (CH₃COCHCOCH₃)Rh(C₆H₅)2PCH₂P(C₆H₅)2 
• 37737-62-5 tris(catecholato)diboron 
• 215254-66-3 (CH₃COCHCOCH₃)Rh(C₆H₅)2PC₅H₄FeC₅H₄P(C₆H₅)2 
• 147142-00-5 (CH₃COCHCOCH₃)Rh(C₆H₅)2PC₄H₈P(C₆H₅)2 
• 132301-74-7 (CH₃COCHCOCH₃)Rh(C₆H₅)2PC₃H₆P(C₆H₅)2 
• 131276-99-8 (CH₃COCHCOCH₃)Rh(C₆H₅)2PC₂H₄P(C₆H₅)2 
• 215254-63-0 (CH₃COCHCOCH₃)Rh[(C₆H₅)2PCH₃]2 

Relevant articles and documents

Rhodium catalysed diboration of unstrained internal alkenes and a new and general route to zwitterionic [L2Rh(η6-catBcat)] (cat = 1,2-O2C6H4) complexes

Reactions of [L2Rh(acac)] (L = alkene or phosphine) with B2cat3 yield the zwitterionic complexes [L2Rh(η6-catBcat)] and [(acac)Bcat] cleanly; [(dppm)Rh(η6-catBcat)), the X-ray structure of which is reported, is an excellent catalyst for the diboration of vinylarenes and unstrained internal alkenes cis- and trans-stilbene and trans-β-methylstyrene.