1350563-96-0Relevant articles and documents
Metal catalyst-free substitution of allylic and propargylic phosphates with diarylmethyl anions
Kawashima, Hidehisa,Ogawa, Narihito,Saeki, Ryohei,Kobayashi, Yuichi
, p. 4918 - 4921 (2016/04/10)
Substitution of secondary allylic phosphates with the anions derived from Ar2CH2 with BuLi or LDA proceeded regioselectively and stereoselectively without a metal catalyst, affording inversion products in good yield. Similarly, propargylic phosphates gave propargylic products selectively.