1350846-02-4

Basic information

• Product Name: (3-methoxyphenyl)methyl methyl carbonate
• Synonyms: (3-methoxyphenyl)methyl methyl carbonate
• CAS NO: 1350846-02-4
• Molecular Weight: 196.203
• Mol File: 1350846-02-4.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (3-methoxyphenyl)methyl methyl carbonate(CAS DataBase Reference)
• NIST Chemistry Reference: (3-methoxyphenyl)methyl methyl carbonate(1350846-02-4)
• EPA Substance Registry System: (3-methoxyphenyl)methyl methyl carbonate(1350846-02-4)

Safety Data

• Hazardous Substances Data: 1350846-02-4(Hazardous Substances Data)

Upstream product

• 6971-51-3 3-methoxybenzyl alcohol 
• 61985-23-7 methyl 1-imidazolecarboxylate 
• 79-22-1 methyl chloroformate 

Downstream Products

• 1350906-67-0 [3-methoxy-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]methyl methyl carbonate 
• 1350846-44-4 3-(3-methoxybenzyl)-3-methyl-3H-indole 
• 1350845-59-8 3-(3-methoxybenzyl)-2,3-dimethyl-3H-indole 
• 1350845-79-2 4a-(3-methoxybenzyl)-2,3,4,4a-tetrahydro-1H-carbazole 
• 1798-09-0 m-methoxyphenylacetic acid 
• 135203-54-2 dimethyl <(3-methoxyphenyl)methyl>phosphonate 

Relevant articles and documents

Palladium-catalyzed benzylic substitution of benzyl carbonates with phosphorus nucleophiles

A wide range of benzyl carbonates reacted with dimethyl phosphonate or diphenylphosphine oxide in the presence of the palladium catalyst, [Pd(η3-allyl)Cl]2DPEphos, to give dimethyl benzylphosphonates and benzyldiphenylphosphine oxides in high yields. The catalytic phosphonylation was applied to the one-pot synthesis of alkenes from the benzyl esters.

Palladium-catalyzed C3-benzylation of indoles

A general method for regioselective C3-benzylation of indoles has been developed. Various 3-substituted indoles and benzyl methyl carbonates with different electronic properties react under mild conditions to afford a diverse range of 3-benzylindolenine products in good yields.