135147-17-0

Basic information

• Product Name: C₂₆H₃₄N₂S₆⁽²⁺⁾*2Br^(1-)
• CAS NO: 135147-17-0
• Molecular Weight: 726.773
• Mol File: 135147-17-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₆H₃₄N₂S₆⁽²⁺⁾*2Br^(1-)(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₆H₃₄N₂S₆⁽²⁺⁾*2Br^(1-)(135147-17-0)
• EPA Substance Registry System: C₂₆H₃₄N₂S₆⁽²⁺⁾*2Br^(1-)(135147-17-0)

Safety Data

• Hazardous Substances Data: 135147-17-0(Hazardous Substances Data)

Upstream product

• 85102-68-7 5-methyl-2-piperidino-4-sulfido-1,3-dithiol-2-ium 
• 626-15-3 1,3-bis-(bromomethyl)benzene 
• 53278-47-0 2(N-piperidino-dithiocarbamoyl) propanoic acid 
• 18474-20-9 piperidinyl-N-carbodithioate anion 

Downstream Products

• 135146-94-0 C₂₆H₂₆S₁₀ 

Relevant articles and documents

Mesoions as Versatile Intermediates in Tetrathiafulvalene Synthesis

Fourteen new alkylthio-substituted tetrathiafulvalene (TTF) donors have been prepared via the mesoionic 2-(N,N-dialkylamino)-5-methyl-1,3-dithiolium-4-thiolates 4.By S-alkylation with alkyl halogenides and alkyl dihalogenides, 4 was transformed into a variety of mono- and bis-1,3-dithiolium salts 5.Coupling of 5 with the anion of 4,5-dimethyl-2H-1,3-dithiole-2-phosphonate ester 6 yielded a series of bis(tetrathiafulvalenes) 2 and (alkylthio)tetrathiafulvalenes 3.By conventional methods, 5 was coupled to bis(alkylthio)tetrathiafulvalenes.The synthesis of 4 was improved.An N,N-dialkyldithiocarbamate salt was allowed to react with a 2-halo carboxylic acid to yield a 1-(carboxyalkyl)-N,N-dialkyldithiocarbamate ester 10, which was then transformed into 4.The electrochemistry of the new TTFs is reported.