1351532-94-9

Basic information

• Product Name: [Ir(2-(2-benzothienyl)pyridinato-C₂,N)2(OOCC₆H₄B(C₆H₂(CH₃)3)2)][tetraethylammonium]
• CAS NO: 1351532-94-9
• Molecular Weight: 1131.32
• Mol File: 1351532-94-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Ir(2-(2-benzothienyl)pyridinato-C₂,N)2(OOCC₆H₄B(C₆H₂(CH₃)3)2)][tetraethylammonium](CAS DataBase Reference)
• NIST Chemistry Reference: [Ir(2-(2-benzothienyl)pyridinato-C₂,N)2(OOCC₆H₄B(C₆H₂(CH₃)3)2)][tetraethylammonium](1351532-94-9)
• EPA Substance Registry System: [Ir(2-(2-benzothienyl)pyridinato-C₂,N)2(OOCC₆H₄B(C₆H₂(CH₃)3)2)][tetraethylammonium](1351532-94-9)

Safety Data

• Hazardous Substances Data: 1351532-94-9(Hazardous Substances Data)

Upstream product

• 1351532-88-1 [Ir(2-(2-benzothienyl)pyridinato-C₂,N)2(OOCC₆H₄B(C₆H₂(CH₃)3)2)][tetraethylammonium] 
• 665-46-3 tetraethylammonium fluoride 

Relevant articles and documents

Turning on MLCT phosphorescence of iridium(III)-borane conjugates upon fluoride binding

The heteroleptic complexes (C∧N)2IrIII (C∧N: ppy, 2; btp, 3), bearing a 4-(dimesitylboryl)benzoate (Bbz) auxiliary ligand, and their fluoride adducts were prepared and characterized. While the PL spectra of 2 and 3 exhibit very weak emission in solution, the addition of fluoride turned on (C∧N)2Ir-centered phosphorescence (λ em 527 nm for 2 and 617 nm for 3). Experimental and DFT calculations suggest that the weak emission is ascribable to a photoinduced electron transfer from the MLCT state of the (C∧N)2Ir moiety to the Bbz ligand and is switched on by fluoride binding to the boron center of the Bbz ligand.