1352404-14-8

Basic information

• Product Name: (7R,8S)-methyl 7,8-bis((S)-2-methoxy-2-phenylacetoxy)tetradecanoate
• Synonyms: (7R,8S)-methyl 7,8-bis((S)-2-methoxy-2-phenylacetoxy)tetradecanoate
• CAS NO: 1352404-14-8
• Molecular Weight: 570.723
• Mol File: 1352404-14-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (7R,8S)-methyl 7,8-bis((S)-2-methoxy-2-phenylacetoxy)tetradecanoate(CAS DataBase Reference)
• NIST Chemistry Reference: (7R,8S)-methyl 7,8-bis((S)-2-methoxy-2-phenylacetoxy)tetradecanoate(1352404-14-8)
• EPA Substance Registry System: (7R,8S)-methyl 7,8-bis((S)-2-methoxy-2-phenylacetoxy)tetradecanoate(1352404-14-8)

Safety Data

• Hazardous Substances Data: 1352404-14-8(Hazardous Substances Data)

Upstream product

• 109537-09-9 (Z)-2-(tetradec-7-en-1-yloxy)tetrahydro-2H-pyran 
• 49592-98-5 (Z)-methyl tetradec-7-enoate 
• 40642-43-1 (Z)-tetradec-7-en-1-ol 
• 4286-55-9 1-bromo-6-hexanol 
• 2430-95-7 (Z)-tetradec-7-enoic acid 
• 53963-10-3 2-[(6-bromohexyl)oxy]tetrahydro-2H-pyran 
• 26164-26-1 (S)-2-methoxy-2-phenylacetic acid 
• 37043-40-6 2-(tetradec-7-yn-1-yloxy)tetrahydro-2H-pyran 

Relevant articles and documents

Synthesis of highly enantioenriched hydroxy- and dihydroxy-fatty esters: Substrate precursors for cytochrome P450BioI

A series of highly enantioenriched hydroxy- and dihydroxy-fatty esters were required as part of our ongoing investigation into cytochrome P450 BioI. This mediates the biosynthesis of pimelic acid via C-C bond cleavage of long chain fatty acids within Bacillus subtilis. Herein we report the synthesis of various stereoisomers of methyl 7-hydroxytetradecanoate, methyl 8-hydroxytetradecanoate, and methyl 7,8-dihydroxytetradecanoate in highly enantioenriched form, using a combination of asymmetric synthesis and a preparative enantioselective HPLC is reported.