1352641-99-6

Basic information

• Product Name: N-phenyl-4-tert-butylbenzamidine
• Synonyms: N-phenyl-4-tert-butylbenzamidine
• CAS NO: 1352641-99-6
• Molecular Weight: 252.359
• Mol File: 1352641-99-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-phenyl-4-tert-butylbenzamidine(CAS DataBase Reference)
• NIST Chemistry Reference: N-phenyl-4-tert-butylbenzamidine(1352641-99-6)
• EPA Substance Registry System: N-phenyl-4-tert-butylbenzamidine(1352641-99-6)

Safety Data

• Hazardous Substances Data: 1352641-99-6(Hazardous Substances Data)

Upstream product

• 4210-32-6 4-tert-butyl benzonitrile 
• 62-53-3 aniline 

Downstream Products

• 1352641-84-9 [(CH₃)5Al₄(N(C₆H₅)C(C₆H₄C(CH₃)3)N)4H] 
• 1352641-84-9 [(CH₃)5Al₄(N(C₆H₅)C(C₆H₄C(CH₃)3)N)4H] 

Relevant articles and documents

Reactions of N-monosubstituted amidines with AlMe3 and AlMeCl2: Formation of fused triazaalane heterocycles

Reactions of N-monosubstituted amidines of the formula HN=C(R)-NH(R′) (R = Ph, 4-tert-butylphenyl, Me; R′ = 2,6-diisopropylphenyl, Ph) with AlMe3 and AlMeCl2 are reported. All the N-(Dipp)amidines (Dipp = 2,6-diisopropylphenyl) react with AlMe3 in a 1:1 ratio to yield tetrameric aluminum amidinates (1, 2, and 3) in good yields. In these compounds, the amidinate ligand chelates to Al while bridging to another Al. However, when N-phenylamidines are employed, tetracyclic (4-9) and pentacyclic (10) Al-N-C heterocycles are formed. In the case of N-phenylbenzamidine, formation of a hexacyclic Al-N-C heterocycle (11) is observed when a slight excess of AlMe 3 (1:1.2 equiv) is used. In these compounds, the amidinate ligand coordinates to Al atoms in a bridging fashion. Further, N-(Dipp)acetamidine and N-(Dipp)benzamidine are also treated with AlMeCl2. Whereas N-(Dipp)acetamidine affords an ionic 15-membered aluminum amidinate chain (12), N-(Dipp)benzamidine gives a bicyclic heterocycle (13) and the AlCl3 adduct of N-(Dipp)benzamidine (14). However, from a reaction between N-phenylbenzamidine and AlMeCl2, only the AlCl3 adduct, 15, was isolated. Compounds 3, 4, 6, 8, and 10-15 have been structurally characterized.