1352710-14-5

Basic information

• Product Name: C₂₇H₃₃N₃
• Synonyms: C₂₇H₃₃N₃
• CAS NO: 1352710-14-5
• Molecular Weight: 399.579
• Mol File: 1352710-14-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₇H₃₃N₃(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₇H₃₃N₃(1352710-14-5)
• EPA Substance Registry System: C₂₇H₃₃N₃(1352710-14-5)

Safety Data

• Hazardous Substances Data: 1352710-14-5(Hazardous Substances Data)

Upstream product

• 134-81-6 benzil 
• 50609-88-6 4,5-diphenyl-1-methyl-1H-imidazole 

Relevant articles and documents

Asymmetric Copper(II)-catalysed nitroaldol (Henry) reactions utilizing a chiral C1-symmetric dinitrogen ligand

A series of stable chiral C1-symmetric dinitrogen ligands were conveniently synthesized in high yields by condensation of chiral amines [(-)-exo-bornylamine or (+)-(1S,2S,5R)-menthylamine] with various substituted imidazolecarbaldehydes. With the assistance of base, the ligand L1 in combination with CuCl2·2H2O (2.5 mol-% or 5.0 mol-%) can efficiently promote nitroaldol (Henry) reactions between a variety of aldehydes and nitromethane. Both aromatic and aliphatic aldehydes were tolerated in our catalytic system, affording the expected nitroalcohol products in high yields (up to 97%) and with good enantioselectivities (up to 96%) under mild reaction conditions. A series of chiral C1-symmetric dinitrogen ligands were conveniently synthesized in high yields by condensations of chiralamines with various substituted imidazolecarbaldehydes. The ligand L1 in conjunction with CuCl2·2H2O can efficiently promote nitroaldol (Henry) reactions between various aldehydes and nitromethane in high yields (up to 97%) and with good enantioselectivities (up to 96%).