1352998-04-9

Basic information

• Product Name: 4-(benzyloxy)butyl acrylate
• Synonyms: 4-(benzyloxy)butyl acrylate
• CAS NO: 1352998-04-9
• Molecular Weight: 234.295
• Mol File: 1352998-04-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-(benzyloxy)butyl acrylate(CAS DataBase Reference)
• NIST Chemistry Reference: 4-(benzyloxy)butyl acrylate(1352998-04-9)
• EPA Substance Registry System: 4-(benzyloxy)butyl acrylate(1352998-04-9)

Safety Data

• Hazardous Substances Data: 1352998-04-9(Hazardous Substances Data)

Relevant articles and documents

Oxidation of acyclic alkenes and allyl and benzyl ethers with DIB/t-BuOOH/Mg(OAc)2

Oxidation of (11Z)-1′,2′-didehydrostemofoline with DIB/TBHP/Mg(OAc)2·4H2O resulted in oxidative cleavage of the C-11-C-12 double bond instead of the desired allylic oxidation of the 1-butenyl side chain. Stemofoline gave a similar result. The oxidation of more simple terminal alkenes was regioselective and gave vinyl ketones while allyl and benzyl ethers gave acrylate and benzoate esters, respectively. Allyl and benzyl ethers could be chemoselectively oxidized in the presence of a terminal alkene or benzyl group. Oxidation of an internal alkene was poorly regioselective, in contrast to the oxidation of 1-substituted cyclohexenes.