1353021-40-5

Basic information

• Product Name: (3S,6R,7R)-6,7-dihydroxy-1-phenylnon-1-yn-3-yl methyl carbonate
• Synonyms: (3S,6R,7R)-6,7-dihydroxy-1-phenylnon-1-yn-3-yl methyl carbonate
• CAS NO: 1353021-40-5
• Molecular Weight: 306.359
• Mol File: 1353021-40-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (3S,6R,7R)-6,7-dihydroxy-1-phenylnon-1-yn-3-yl methyl carbonate(CAS DataBase Reference)
• NIST Chemistry Reference: (3S,6R,7R)-6,7-dihydroxy-1-phenylnon-1-yn-3-yl methyl carbonate(1353021-40-5)
• EPA Substance Registry System: (3S,6R,7R)-6,7-dihydroxy-1-phenylnon-1-yn-3-yl methyl carbonate(1353021-40-5)

Safety Data

• Hazardous Substances Data: 1353021-40-5(Hazardous Substances Data)

Upstream product

• 62238-34-0 5-hepten-1-al 

Downstream Products

• 1353021-56-3 (R)-1-((2R,5S)-5-(phenylethynyl)tetrahydrofuran-2-yl)propan-1-ol 
• 1353021-85-8 (2R,2'R,5S,5'R)-5-(6-(benzyloxy)hex-1-yn-1-yl)-5'-(phenylethynyl)octahydro-2,2'-bifuran 

Relevant articles and documents

Palladium-catalyzed asymmetric synthesis of 2-alkynyl oxacycles

Oxyacetylene: Unusual palladium-catalyzed cyclizations of cyclic and acyclic propargylic carbonates give 2-alkynyl oxacycles. The reactions proceed with very high stereoselectivity for both syn- and anti-disubstituted furans and pyrans, and with exceptional regioselectivity. In addition, two-directional cyclizations of bis-propargylic carbonate substrates yield bifurans with complete stereocontrol for all diastereomers.