1353023-74-1

Basic information

• Product Name: rac-tert-butyl-{3-[(1E,3E,5E,7E)-3,7-dimethyldeca-1,3,5,7,9-pentaenyl]-2,4,4-trimethylcyclohex-2-enyloxy}dimethylsilane
• Synonyms: rac-tert-butyl-{3-[(1E,3E,5E,7E)-3,7-dimethyldeca-1,3,5,7,9-pentaenyl]-2,4,4-trimethylcyclohex-2-enyloxy}dimethylsilane
• CAS NO: 1353023-74-1
• Molecular Weight: 412.731
• Mol File: 1353023-74-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: rac-tert-butyl-{3-[(1E,3E,5E,7E)-3,7-dimethyldeca-1,3,5,7,9-pentaenyl]-2,4,4-trimethylcyclohex-2-enyloxy}dimethylsilane(CAS DataBase Reference)
• NIST Chemistry Reference: rac-tert-butyl-{3-[(1E,3E,5E,7E)-3,7-dimethyldeca-1,3,5,7,9-pentaenyl]-2,4,4-trimethylcyclohex-2-enyloxy}dimethylsilane(1353023-74-1)
• EPA Substance Registry System: rac-tert-butyl-{3-[(1E,3E,5E,7E)-3,7-dimethyldeca-1,3,5,7,9-pentaenyl]-2,4,4-trimethylcyclohex-2-enyloxy}dimethylsilane(1353023-74-1)

Safety Data

• Hazardous Substances Data: 1353023-74-1(Hazardous Substances Data)

Upstream product

• 18162-48-6 tert-butyldimethylsilyl chloride 
• 1353023-71-8 rac-all-trans-4-(tert-butyldimethylsilyloxy)retinal 
• 1779-49-3 Methyltriphenylphosphonium bromide 
• 1353023-70-7 rac-all-trans-4-(tert-butyldimethylsilyloxy)retinol 
• 1353023-69-4 rac-(E)-tert-butyl-[3-(2-iodovinyl)-2,4,4-trimethylcyclohex-2-enyloxy]dimethylsilane 
• 817203-15-9 rac-(E)-3-(2-iodovinyl)-2,4,4-trimethylcyclohex-2-en-1-ol 

Downstream Products

• 29065-03-0 isozeaxanthin 

Relevant articles and documents

Synthesis of C40-symmetrical fully conjugated carotenoids by olefin metathesis

In an effort to push olefin metathesis to the limits of conjugation in reactants and products, the C40-symmetrical carotenoids β,β-carotene (1), lycopene (2), (3R,3′R)-zeaxanthin (3), and rac-isozeaxanthin (4), which are conjugated undecaenes, have been synthesized from C21-terminal hexaenes by treatment with Grubbs' second-generation Ru catalyst in dichloromethane at 50 °C.