1353221-23-4Relevant articles and documents
Nickel(0) catalyzed oxidation of organosilanes to disiloxanes by air as an oxidant
Lv, Haiping,Laishram, Ronibala Devi,Li, Jiayan,Shi, Guangrui,Sun, Weiqing,Xu, Jianbin,Yang, Yong,Luo, Yang,Fan, Baomin
, p. 971 - 974 (2019)
We report here an efficient non-aqueous route to symmetrical disiloxanes from their corresponding organosilanes using Ni(COD)2 with 3,4,7,8-tetramethyl-1,10-phenanthroline in air. Our methodology is very simple and high yielding. The reaction mechanism is also proposed.