1354723-64-0

Basic information

• Product Name: (S,Z)-tert-butyl [4-(hydroxymethyl)-3-phenyl-3-butene-2-yl]carbamate
• Synonyms: (S,Z)-tert-butyl [4-(hydroxymethyl)-3-phenyl-3-butene-2-yl]carbamate
• CAS NO: 1354723-64-0
• Molecular Weight: 277.364
• Mol File: 1354723-64-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S,Z)-tert-butyl [4-(hydroxymethyl)-3-phenyl-3-butene-2-yl]carbamate(CAS DataBase Reference)
• NIST Chemistry Reference: (S,Z)-tert-butyl [4-(hydroxymethyl)-3-phenyl-3-butene-2-yl]carbamate(1354723-64-0)
• EPA Substance Registry System: (S,Z)-tert-butyl [4-(hydroxymethyl)-3-phenyl-3-butene-2-yl]carbamate(1354723-64-0)

Safety Data

• Hazardous Substances Data: 1354723-64-0(Hazardous Substances Data)

Upstream product

• 1354723-21-9 (S)-5-(methoxymethoxy)-3-penynyl diphenyl phosphate 
• 1354723-29-7 (S)-5-(methoxymethoxy)pent-3-yn-2-ol 
• 1354723-63-9 (S)-tert-butyl 3-methyl-5-(2-phenyl)-1,2-oxazine-2-carboxylate 

Downstream Products

• 15761-38-3 L-N-Boc-Ala 
• 51814-46-1 2-oxo-2-phenylethyl (tert-butoxycarbonyl)-L-alaninate 

Relevant articles and documents

Synthesis of conjugated allenes through copper-catalyzed γ-selective and stereospecific coupling between propargylic phosphates and aryl- or alkenylboronates

A Cu-catalyzed γ-selective coupling reaction between propargylic phosphates and aryl- or alkenylboronates afforded aryl- or alkenyl-conjugated allenes. The reaction showed excellent functional group compatibility in both the propargylic substrates and the boronates. The reaction of an enantioenriched propargylic phosphate proceeded with excellent chirality transfer with 1,3-anti stereochemistry to give axially chiral aryl- and alkenylallenes.