13557-24-9

Basic information

• Product Name: Benzene, [(1-chloroethyl)thio]-
• CAS NO: 13557-24-9
• Molecular Formula: C8H9ClS
• Molecular Weight: 172.678
• Mol File: 13557-24-9.mol
• Article Data: 15

Chemical Properties

• CAS DataBase Reference: Benzene, [(1-chloroethyl)thio]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(1-chloroethyl)thio]-(13557-24-9)
• EPA Substance Registry System: Benzene, [(1-chloroethyl)thio]-(13557-24-9)

Safety Data

• Hazardous Substances Data: 13557-24-9(Hazardous Substances Data)

Upstream product

• 75-07-0 acetaldehyde 
• 108-98-5 thiophenol 
• 1822-73-7 phenylthioethylene 
• 13307-56-7 1,1-bis(phenylthio)ethane 
• 622-38-8 Ethyl phenyl sulfide 

Downstream Products

• 16158-83-1 1-methyl-2-phenylethenyl phenyl sulfide 
• 56819-81-9 erythro-1-Phenyl-2-phenylthio-1-propanol 
• 108033-48-3 threo-1-Phenyl-2-phenylthio-1-propanol 
• 7594-43-6 isopropenyl phenyl sulfide 
• 56819-81-9 threo-1-Phenyl-2-phenylthio-1-propanol 
• 56819-81-9 erythro-1-Phenyl-2-phenylthio-1-propanol 
• 1822-73-7 phenylthioethylene 
• 13557-25-0 1-(1-chloroethyl)phenyl sulfone 
• 344884-21-5 2-ethyl-2-methyl-3-phenylthiobutanal 
• 124456-62-8 Acetic acid (4aS,4bS,7R,8aR,9S,10aR)-1,1,4a,7-tetramethyl-6-oxo-7-(1-phenylsulfanyl-ethyl)-tetradecahydro-phenanthren-9-yl ester 
• 83039-98-9 (E)-5-Phenylsulfanyl-hex-2-enoic acid methyl ester 
• 82202-05-9 4-methyl-3-(1-phenylthioethyl)-4-trimethylsilyloctan-2-one 
• 138225-49-7 (1S,1'RS,3aS,4RS,7aS)-1-tert-Butoxy-4-(1'-phenylthioethyl)-7a-methyl-3a,4,7,7a-tetrahydro-5⁽⁶⁾-indan-5-one 
• 138225-47-5 trans-3-Methyl-2-(1'-phenylthioethyl)cyclopentanone 

Relevant articles and documents

Preparation and reactions of functionalized magnesium carbenoids

New functionalized magnesium carbenoids bearing an ester function have been prepared via an iodine-magnesium exchange reaction. These new carbenoids react with various electrophiles (60-88% yield). A substituted magnesium carbenoid has been prepared by su

Thioalkylation of Enolates, IV. α-Alkylidenecyclopentanones by α-Alkylidation of Methyl 2-Oxocyclopentanecarboxylate

An α-alkylidation of cyclopentanone was achieved in two reaction steps in an overall yield of 20 to 79percent via a zinc chloride-catalyzed thioalkylation of the zinc enolate of methyl 2-oxocyclopentanecarboxylate (3) and subsequent saponification/desulfurization of the β-(phenylthio) ketone intermediates 5.For the saponification/desulfurization step DABCO proved to be the reagent of choice and superior to the use of alkali or magnesium halides. - Key Words: Zinc enolates, thioalkylation of / Cyclopentanones, α-alkylidene

ZINC(II)-CHLORIDE INDUCED THIOALKYLATION OF ALUMINIUM ENOLATES; ENANTIOSELECTIVE SYNTHESIS OF ESTRADIOL-3-METHYL-17-tert-BUTYL DIETHER

Zinc(II)-chloride induced thioalkylation of the aluminium enolate 6 generated by conjugate reduction of the enone 5 leads - directly or via its trimethylsilylenol ether 6 - to alkylated hydrindanones 10 which are important intermediates in the synthesis o