1355956-49-8Relevant articles and documents
Acceleration effects of phosphine ligands on the rhodium-catalyzed dehydrogenative silylation and germylation of unactivated C(sp3)-H bonds
Murai, Masahito,Takeshima, Hirotaka,Morita, Haruka,Kuninobu, Yoichiro,Takai, Kazuhiko
, p. 5407 - 5414 (2015/06/16)
The current work describes the marked rate of acceleration caused by phosphine ligands on the rhodium-catalyzed dehydrogenative silylation and germylation of unactivated C(sp3)-H bonds. The reactivity was affected by the steric and electronic n
Silylboranes as new sources of silyl radicals for chain-transfer reactions
Rouquet, Guy,Robert, Frederic,Mereau, Raphaal,Castet, Frederic,Renaud, Philippe,Landais, Yannick
, p. 940 - 950 (2012/02/16)
Various silylboranes, which were outfitted with a catecholborane moiety at one end and a (Me3Si)3Si moiety at the other end of a carbon chain, were prepared through the hydroboration of the corresponding unsaturated silanes. The C-ce