1356155-30-0Relevant articles and documents
Free-radical hydrothiolation of glycals: A thiol-ene-based synthesis of S-disaccharides
Staderini, Samuele,Chambery, Angela,Marra, Alberto,Dondoni, Alessandro
, p. 702 - 704 (2012)
A method for the synthesis of a new family of 1-deoxy S-disaccharides has been established via free-radical hydrothiolation of glycals by sugar thiols (thiol-ene coupling). The photoinduced coupling between four tri-O-acetyl-d-glycals and three different sugar thiols reveals that the reaction efficiency and stereoselectivity are highly dependent on the stereochemistry of the OAc groups at C3 and C4 of the glycal.