13562-76-0

Basic information

• Product Name: ACETOACETIC ACID SEC-BUTYL ESTER
• Synonyms: ACETOACETIC ACID SEC-BUTYL ESTER;SEC-BUTYL ACETOACETATE;(R,S)-3-Oxo-butyricacidsec-butylester;R,S-3-Oxo-butyricacidsec-butylester;Sec-butyl 3-oxobutanoate;ACETOACETICSEC-BUTYLESTER;Acetoacetic acid 1-methylpropyl ester;sec-Butyl Acetaoacetate
• CAS NO: 13562-76-0
• Molecular Formula: C₈H₁₄O₃
• Molecular Weight: 158.19
• Mol File: 13562-76-0.mol
• Article Data: 8

Chemical Properties

• Boiling Point: 194 °C
• Flash Point: 75.7 °C
• Appearance: /
• Density: 0.98
• Vapor Pressure: 0.342mmHg at 25°C
• Refractive Index: 1.4210-1.4240
• CAS DataBase Reference: ACETOACETIC ACID SEC-BUTYL ESTER(CAS DataBase Reference)
• NIST Chemistry Reference: ACETOACETIC ACID SEC-BUTYL ESTER(13562-76-0)
• EPA Substance Registry System: ACETOACETIC ACID SEC-BUTYL ESTER(13562-76-0)

Safety Data

• Hazardous Substances Data: 13562-76-0(Hazardous Substances Data)

Usage

General Description

ACETOACETIC ACID SEC-BUTYL ESTER is a chemical compound that is commonly used as a solvent in various industrial and laboratory applications. It is also used as a flavoring agent in food products and as a fragrance ingredient in perfumes and cosmetics. The compound is known for its fruity odor and is commonly used as a component in the production of artificial fruit flavors. Additionally, ACETOACETIC ACID SEC-BUTYL ESTER is used in the synthesis of pharmaceuticals, pesticides, and other organic compounds, making it a versatile and important chemical in the manufacturing and production of various products.

InChI:InChI=1/C8H14O3/c1-4-7(3)11-8(10)5-6(2)9/h7H,4-5H2,1-3H3

Upstream product

• 141-97-9 ethyl acetoacetate 
• 78-92-2 iso-butanol 
• 105-46-4 sec-Butyl acetate 
• 105-45-3 acetoacetic acid methyl ester 
• 5394-63-8 2,2,6-trimethyl-4H-1,3-dioxin-4-one 
• 674-82-8 4-methyleneoxetan-2-one 
• 2911-21-9 2,4-dioxo-6-methyl-3,4-dihydro-2H-1,3-oxazine 

Downstream Products

• 95549-56-7 2,5-di-α-methylpropylformate 1,4-cyclohexanedione 
• 116679-99-3 2-(3-Nitrophenylmethylidene)-3-oxobutanoic acid, 1-methylpropyl ester 

Relevant articles and documents

Nano CuFe2O4: An efficient, magnetically separable catalyst for transesterification of β-ketoesters

The preparation of a variety of β-ketoesters was achieved in high yields from methyl acetoacetate under neutral conditions through the utilization of magnetic CuFe2O4 nanoparticles as catalyst. Recycling of the catalyst was performed up to eight times without significant loss in activity. The catalyst was characterized using XRD, XPS, SEM and TEM techniques.

BF3OEt2: An efficient catalyst for transesterification of β-ketoesters

A facile and selective transesterification of β-ketoesters using BF3OEt2 as catalyst is described. The emphasis has been placed on the reaction of methyl acetoacetate with a series of alcohols of different structures, leading in all cases to good to excellent yields.

Mo-ZrO2 solid acid catalyst for transesterification of β-ketoesters

An efficient and mild method for transesterification of β-ketoester catalyzed by Mo-ZrO2 solid acid catalyst is described.