1356238-72-6Relevant articles and documents
Bis(phosphoryl)-bridged biphenyls by radical phosphanylation: Synthesis and photophysical and electrochemical properties
Bruch, Achim,Fukazawa, Aiko,Yamaguchi, Eriko,Yamaguchi, Shigehiro,Studer, Armido
, p. 12094 - 12098 (2012/02/02)
The efficient fourfold radical phosphanylation of 2,2,2′,2′- tetrabromobiphenyl with a bis(stannyl)phosphane followed by oxidation produces a highly strained biphenyl with two phosphoryl bridges (see picture). Extended π-conjugated compounds consisting of this core unit can be also synthesized by using the same approach. The two phosphoryl bridges significantly alter the electronic structure, making this biphenyl a unique electron-accepting scaffold. Copyright