1356339-86-0Relevant articles and documents
Polycyclic bridgehead acetals with enol functionality: one-pot assembly from aliphatic ketones and acetylene in KOH/DMSO suspension
Schmidt, Elena Yu.,Bidusenko, Ivan A.,Cherimichkina, Natalia A.,Ushakov, Igor A.,Trofimov, Boris A.
, p. 4510 - 4517 (2016)
Aliphatic and cycloaliphatic ketones undergo selective multi-site cascade C–H functionalization with acetylene in the KOH/DMSO superbase suspension under mild conditions (70–80?°C, 0.5–1.0?h) to afford in one synthetic operation polycyclic bridgehead acet
Base-catalyzed O-vinylation of tertiary propargylic alcohols with acetylene: First examples
Trofimov, Boris A.,Schmidt, Elena Yu.,Skital'Tseva, Elena V.,Bidusenko, Ivan A.,Zorina, Nadezhda V.,Mikhaleva, Al'Bina I.
, p. 62 - 63 (2012)
1-Ethynylcyclohexanol and 1-ethynylcycloheptanol are O-vinylated with acetylene in KOH/DMSO superbase system (90°C, autoclave, initial acetylene pressure of 14 atm, 1 h) to afford the corresponding vinyl ethers in 40 and 34% yields, respectively.
