135637-10-4

Basic information

• Product Name: (1S,2S)-<2-2H>-1-phenylpropan-1-ol
• CAS NO: 135637-10-4
• Molecular Weight: 137.186
• Mol File: 135637-10-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (1S,2S)-<2-2H>-1-phenylpropan-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (1S,2S)-<2-2H>-1-phenylpropan-1-ol(135637-10-4)
• EPA Substance Registry System: (1S,2S)-<2-2H>-1-phenylpropan-1-ol(135637-10-4)

Safety Data

• Hazardous Substances Data: 135637-10-4(Hazardous Substances Data)

Upstream product

• 1325730-35-5 (1S,2S)-2-deutero-4,4,5,5-tetramethyl-2-(1-phenylpropyl)-1,3,2-dioxaborolane 
• 14212-54-5 (+)-(R,R)-β-methylstyrene oxide 
• 73738-40-6 ethyl benzoylacetate-d2 
• 73738-41-7 <2-2H2>-1-phenylpropane-1,3-diol 
• 34236-34-5 α,α-dideutero-β-chloropropiophenone 
• 135561-72-7 (2S)-<2-2H>-propiophenone 
• 23355-97-7 1-phenylpropylene oxide 
• 135561-74-9 Toluene-4-sulfonic acid (1S,2R)-2-hydroxy-1-methyl-2-phenyl-ethyl ester 
• 135561-71-6 <2-2H2>-3-chloro-1-phenylpropan-1-ol 
• 94-02-0 ethyl 3-oxo-3-phenylpropionate 
• 100-52-7 benzaldehyde 
• 40421-52-1 (1R,2S)-1-phenylpropane-1,2-diol 

Downstream Products

• 135561-79-4 (1RS,2S)-<2-2H>-1-phenyl-1-acetoxypropane 
• 135637-08-0 C₉H₁₁⁽²⁾HO 
• 135561-73-8 C₁₁H₁₃⁽²⁾HO₂ 

Relevant articles and documents

An efficient copper(I)-catalyst system for the asymmetric hydroboration of β-substituted vinylarenes with pinacolborane

The pinacol of ligands: The (R)-DTBM-Segphos coordinated copper(I) complex was found to be very effective for the asymmetric hydroboration of β-substituted styrene derivatives with pinacolborane (see scheme; DTBM=3,5-di-tert-butyl-4-methoxyphenyl). This new method affords benzylic pinacol boronate esters with excellent levels of regio- and enantioselectivity (>99 %).

CONFORMATIONAL ANALYSIS OF AMPHETAMINE IN SOLUTION BASED ON UNAMBIGUOUS ASSIGNMENT OF THE DIASTEREOTOPIC BENZYLIC PROTONS IN THE (1)H NMR SPECTRA

The erythro- and threo-amphetamine-β-d diastereomers were synthesized and used for the unambiguous assignment of the diastereotopic benzylic protons and the mesurement of vicinal (1)H-(1)H coupling constants which were used to determine the distribution of rotamers around the central Cα-Cβ bond in the side chain.