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1356966-10-3

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1356966-10-3 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 1356966-10-3 includes 10 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 7 digits, 1,3,5,6,9,6 and 6 respectively; the second part has 2 digits, 1 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 1356966-10:
(9*1)+(8*3)+(7*5)+(6*6)+(5*9)+(4*6)+(3*6)+(2*1)+(1*0)=193
193 % 10 = 3
So 1356966-10-3 is a valid CAS Registry Number.

1356966-10-3Upstream product

1356966-10-3Downstream Products

1356966-10-3Relevant articles and documents

B(C6F5)3-Catalyzed Deoxygenative Reduction of Amides to Amines with Ammonia Borane

Pan, Yixiao,Luo, Zhenli,Han, Jiahong,Xu, Xin,Chen, Changjun,Zhao, Haoqiang,Xu, Lijin,Fan, Qinghua,Xiao, Jianliang

, p. 2301 - 2308 (2019)

The first B(C6F5)3-catalyzed deoxygenative reduction of amides into the corresponding amines with readily accessible and stable ammonia borane (AB) as a reducing agent under mild reaction conditions is reported. This metal-free protocol provides facile access to a wide range of structurally diverse amine products in good to excellent yields, and various functional groups including those that are reduction-sensitive were well tolerated. This new method is also applicable to chiral amide substrates without erosion of the enantiomeric purity. The role of BF3 ? OEt2 co-catalyst in this reaction is to activate the amide carbonyl group via the in situ formation of an amide-boron adduct. (Figure presented.).

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