1357059-20-1

Basic information

• Product Name: (E)-N-allyl-N-(3-hydroxybut-1-enyl)-4-methylbenzenesulfonamide
• Synonyms: (E)-N-allyl-N-(3-hydroxybut-1-enyl)-4-methylbenzenesulfonamide
• CAS NO: 1357059-20-1
• Molecular Weight: 281.376
• Mol File: 1357059-20-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (E)-N-allyl-N-(3-hydroxybut-1-enyl)-4-methylbenzenesulfonamide(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-N-allyl-N-(3-hydroxybut-1-enyl)-4-methylbenzenesulfonamide(1357059-20-1)
• EPA Substance Registry System: (E)-N-allyl-N-(3-hydroxybut-1-enyl)-4-methylbenzenesulfonamide(1357059-20-1)

Safety Data

• Hazardous Substances Data: 1357059-20-1(Hazardous Substances Data)

Upstream product

• 1357059-18-7 (E)-N-allyl-4-N-(3-oxobut-1-enyl)-4-methylbenzenesulfonamide 

Downstream Products

• 1357059-22-3 (E)-4-(N-allyl-4-methylphenylsulfonamido)but-3-en-2-yl 3-methylbutanoate 
• 1357059-25-6 (E)-4-(N-allyl-4-methylphenylsulfonamido)but-3-en-2-yl 2-phenylacetate 
• 1357059-27-8 (E)-4-(N-allyl-4-methylphenylsulfonamido)but-3-en-2-yl 2-(4-methoxyphenyl)acetate 

Relevant articles and documents

Si-free enolate Claisen rearrangements of enamido substrates

α-Alkyl β-amino esters are available in high diastereoselectivity through a silicon-free Claisen enolate [3,3]-sigmatropic rearrangement of enamide esters. Optimisation studies have probed the crucial role of the initial enolisation and the nature of the enamide N-centre. The demonstration of chirality transfer and the formation of β-proline systems, is also presented.